five

Exploring Skeletal Diversity via Ring Contraction of Glycal-Derived Scaffolds

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Exploring_Skeletal_Diversity_via_Ring_Contraction_of_Glycal_Derived_Scaffolds/3051709
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Aryl ether C-glycoside scaffolds have been prepared from tri-O-acetyl-d-glucal by C-glycosylation followed by allylic substitution with phenols mediated by Pd(0). The aryl ethers were subjected to either [3,3]-sigmatropic rearrangement to produce 3-pyranyl-phenols or Au(III)-mediated ring contraction to create highly substituted tetrahydrofurans.
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2016-02-29
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