Total Synthesis of (+)-Aplykurodinone‑1
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https://figshare.com/articles/dataset/Total_Synthesis_of_-Aplykurodinone_1/5363743
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资源简介：
Starting
from (R)-citronellic acid and (R)-seudenol, the total synthesis of (+)-aplykurodinone-1,
a highly degraded marine steroid, has been achieved in 11 steps and
in 19% overall yield with excellent stereochemical control. In addition
to the features such as an Ireland–Claisen rearrangement, an
intramolecular carbonyl–ene cyclization, and an intramolecular
Michael addition, the present synthetic strategy is accomplished without
the use of protecting groups.
创建时间：
2017-08-31
