Three-Coordinate Iron(II) N-Heterocyclic Carbene Alkyl Complexes
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https://figshare.com/articles/dataset/Three_Coordinate_Iron_II_N_Heterocyclic_Carbene_Alkyl_Complexes/2515465
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资源简介：
Mononuclear alkyl N-heterocyclic carbene complexes of
the type
Fe(NHC)R2, NHC = SIPri, IPri, R =
CH2SiMe3, CH2C6H5, were prepared by the alkylation of “FeCl2(THF)1.5” with one equivalent per Fe of MgR2,
in the presence of the NHC. Alkylation with 0.5 equiv of MgR2 under carefully controlled conditions gave Fe(NHC)(CH2SiMe3)Cl, NHC = SIPri, IPri. Magnetic
and computational studies and structural determination by X-ray diffraction
reveal three-coordinate high-spin (S = 2) alkyl complexes.
创建时间：
2016-02-20
