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Ru/Cu Photoredox or Cu/Ag Catalyzed C4–H Sulfonylation of 1‑Naphthylamides at Room Temperature

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Figshare2017-11-01 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ru_Cu_Photoredox_or_Cu_Ag_Catalyzed_C4_H_Sulfonylation_of_1_Naphthylamides_at_Room_Temperature/5561701
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A mild and efficient protocol for C4–H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates has been described. This C4 sulfonylation proceeded smoothly at room temperature under Ru/Cu photoredox catalysis or Cu/Ag cocatalysis and could tolerate various functional groups. In addition, control experiments suggested that this C4–H sulfonylation reaction might proceed via a single-electron-transfer process.
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2017-11-01
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