Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid
收藏NIAID Data Ecosystem2026-03-13 收录
下载链接：
https://figshare.com/articles/dataset/Distinct_Reactivity_Modes_of_a_Copper_Hydride_Enabled_by_an_Intramolecular_Lewis_Acid/20483926
下载链接
链接失效反馈官方服务：
资源简介：
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring
an
appended boron Lewis acid. Metalation with Cu(I) affords a series
of tetrahedral complexes including a boron-capped cuprous hydride.
We demonstrate distinct reactivity modes as a function of chemical
oxidation: hydride transfer to CO2 in the copper(I) state
and oxidant-induced H2 evolution as well as alkyne reduction.
创建时间：
2022-08-12
