An Unusual Zwitterionic, Diradical Intermediate in Photochemical Electron-Transfer Substitution Reactions
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https://figshare.com/articles/dataset/An_Unusual_Zwitterionic_Diradical_Intermediate_in_Photochemical_Electron_Transfer_Substitution_Reactions/3321004
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资源简介：
An unusual zwitterionic diradical intermediate complex R•···X-···HR‘B•+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR‘B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25 K by electron spin resonance spectroscopy. Ab initio density functional calculations were carried out to examine the physical and electronic structure of the intermediate.
创建时间：
2016-05-06
