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Synthesis and Crystallographic Characterization of a Novel Platinocycle

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https://figshare.com/articles/dataset/Synthesis_and_Crystallographic_Characterization_of_a_Novel_Platinocycle/3763308
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The efficient synthesis and characterization of the trans-platinum complex (Ph3P)2Pt(C25H13N) by coupling the dialkyne 3,5-bis-(2-ethynyl-phenylethynyl)pyridine with cis-PtCl2(PPh3)2 is described. The X-ray crystal structure shows that the platinum center is essentially square planar with the two phosphine ligands mutually perpendicular to the planar organic ligand.
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2016-08-26
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