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Simple Polyphenyl Zirconium and Hafnium Metallocene Room-Temperature Lumophores for Cell Imaging

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Simple_Polyphenyl_Zirconium_and_Hafnium_Metallocene_Room_Temperature_Lumophores_for_Cell_Imaging/2402740
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Zirconium and hafnium metallocene dihalides based on simple polyphenyl cyclopentadienes are stable room-temperature lumophores with large Stokes shifts, emitting from states with substantial LMCT character. Their synthesis is described, including by a rapid solvent-free approach compatible with the lifetime of PET-active isotopes (89Zr). Preliminary experiments indicate the viability of these species as lumophores for fluorescence cell-imaging microscopy.
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2016-02-19
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