Merging Two Functions in a Single Rh Catalyst System: Bimodular Conjugate for Light-Induced Oxidative Coupling
收藏NIAID Data Ecosystem2026-03-12 收录
下载链接：
https://figshare.com/articles/dataset/Merging_Two_Functions_in_a_Single_Rh_Catalyst_System_Bimodular_Conjugate_for_Light-Induced_Oxidative_Coupling/13169309
下载链接
链接失效反馈官方服务：
资源简介：
A single molecular rhodium catalyst
system (PC2-Cp#RhIII) bearing two functional
domains for both photosensitization
and C–H carbometalation was designed to enable an intramolecular
redox process. The hypothesized charge-transfer species (PC2•–-Cp#RhIV) was characterized by spectroscopic
and electrochemical analyses. This photoinduced internal oxidation
allows a facile access to the triplet state of the key post-transmetalation
intermediate that readily undergoes C–C bond-forming reductive
elimination with a lower activation barrier than in its singlet state,
thus enabling catalytic C–H arylation and methylation processes.
创建时间：
2020-10-30
