Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage
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https://figshare.com/articles/dataset/Preparing_Multi_Fluoroarenes_as_Building_Blocks_for_Synthesis_Nickel_Catalyzed_Borylation_of_Polyfluoroarenes_via_C_F_Bond_Cleavage/3180991
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The [Ni(IMes)2]-catalyzed transformation of fluoroarenes into arylboronic acid pinacol esters via C–F bond activation and transmetalation with bis(pinacolato)diboron (B2pin2) is reported. Various partially fluorinated arenes with different degrees of fluorination were converted into their corresponding boronate esters.
创建时间:
2016-04-21



