Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex
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https://figshare.com/articles/dataset/Asymmetric_Cross_Dimerization_between_Methyl_Methacrylate_and_Substituted_Alkene_by_Ru_0_Bicyclononadiene_Complex/2414272
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资源简介：
New Ru(0)–naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,S)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer in 74% yield in 80% ee.
创建时间：
2016-02-19
