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An Extremely Air-Stable 19π Porphyrinoid

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/An_Extremely_Air_Stable_19_Porphyrinoid/2145910
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A one-electron reduced species of a cationic phosphorus­(V) tetraazaporphyrin complex has been isolated as an air-stable solid. Cyclic voltammetry and magnetic measurements showed the species to be a neutral π radical, and the solid state structure was elucidated by single crystal X-ray diffraction analysis. Magnetic circular dichroism spectroscopy and theoretical calculations also support a 19π electron conjugated electronic circuit.
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2016-02-13
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