An Extremely Air-Stable 19π Porphyrinoid
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下载链接:
https://figshare.com/articles/dataset/An_Extremely_Air_Stable_19_Porphyrinoid/2145910
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资源简介:
A one-electron reduced species of
a cationic phosphorus(V) tetraazaporphyrin
complex has been isolated as an air-stable solid. Cyclic voltammetry
and magnetic measurements showed the species to be a neutral π
radical, and the solid state structure was elucidated by single crystal
X-ray diffraction analysis. Magnetic circular dichroism spectroscopy
and theoretical calculations also support a 19π electron conjugated
electronic circuit.
创建时间:
2016-02-13



