Insights into the Formation of Borabenzene Adducts via Ligand Exchange Reactions and TMSCl Elimination from Boracyclohexadiene Precursors
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https://figshare.com/articles/dataset/Insights_into_the_Formation_of_Borabenzene_Adducts_via_Ligand_Exchange_Reactions_and_TMSCl_Elimination_from_Boracyclohexadiene_Precursors/2274952
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资源简介：
The
bonding properties of borabenzene with various neutral Lewis bases
have been investigated. 1-Chloro-4-isopropyl-2-(trimethylsilyl)-2,4-boracyclohexadiene
reacts with a number of Lewis basesnotably pyridine, PMe3, PCy3, and PPh3to afford 4-isopropylborabenzene–base
adducts. These adducts can undergo ligand exchange to afford new borabenzene
complexes. The scope and mechanism of the reaction, as well as the
steric and electronic properties of different adducts, were studied
experimentally and computationally.
创建时间：
2016-02-17
