Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity
收藏Figshare2019-01-30 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cycloosmathioborane_Compounds_Other_Manifestations_of_the_Hu_ckel_Aromaticity/7649462
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The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH3NHR2 amine–borane, bear an Os–S–B three-membered ring, being a manifestation of the 4n + 2 Hückel aromaticity in which n = 0 and where the two π electrons of the ring are provided by the S atom.
创建时间:
2019-01-30



