Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity
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The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH3NHR2 amine–borane, bear an Os–S–B three-membered ring, being a manifestation of the 4n + 2 Hückel aromaticity in which n = 0 and where the two π electrons of the ring are provided by the S atom.
创建时间：
2019-01-30
