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Structures of Lithium Ferrocenylenecuprates and Their Oxidative Coupling Reactions

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NIAID Data Ecosystem2026-03-06 收录
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Lithium ferrocenylenecuprate has been prepared from the treatment of ferrocene with butyllithium and copper(I) mesityl. Depending upon the choice of base (nBuLi/tmeda or tBuLi), one of two different cuprate complexes is obtained, both of which have been characterized using X-ray crystallography to reveal unique trimetallic clusters. In addition, lithium ferrocenylenecuprate is shown to undergo oxidative coupling to give poly-1,1′-ferrocenylene.

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2016-02-26
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