Asymmetric Total Synthesis of (−)-Spirochensilide A
收藏NIAID Data Ecosystem2026-03-11 收录
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_-Spirochensilide_A/12156318
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资源简介：
An asymmetric total synthesis of
(−)-spirochensilide A has
been achieved for the first time. The synthesis features a semipinacol
rearrangement reaction to stereoselectively construct the two-vicinal
quaternary chiral centers at C8 and C10, a tungsten-mediated cyclopropene-based
Pauson–Khand reaction to install the C13 quaternary chiral
center, and a furan-based oxidative cyclization to stereoselectively
form the spiroketal motif.
创建时间：
2020-04-14
