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Gondola-Shaped Luminescent Tetrarhenium Metallacycles with Crown-Ether-like Multiple Recognition Sites

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NIAID Data Ecosystem2026-03-06 收录
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The self-assembly of gondola-shaped tetrarhenium metallacyclophanes was achieved in near quantitative yield from Re(CO)3 corners, a ditopic heterocyclic clip, and a bischelating-bridging unit using an orthogonal-bonding approach. The highly luminescent metallacycles contain crown-ether-like recognition sites, which are capable of selectively recognizing metal ions and planar aromatic molecules.

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2016-02-29
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