Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes
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https://figshare.com/articles/dataset/Sumanenyl_Metallocenes_Synthesis_and_Structure_of_Mono_and_Trinuclear_Zirconocene_Complexes/2256031
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资源简介:
Mono-
and trinuclear sumanenyl zirconocene complexes Cp(sumanenyl)ZrCl2, Cp*(sumanenyl)ZrCl2, and (C21H9)[(Cp*)ZrCl2]3 were successfully synthesized.
In the mononuclear complexes, convex binding with disturbed η5-bonding was confirmed in a solid state. As demonstrated in
the trinuclear complex, the multibenzylic anion of sumanene offers
a novel ligand for the multinuclear metallocenes.
创建时间:
2014-09-10



