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Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

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https://figshare.com/articles/dataset/Sumanenyl_Metallocenes_Synthesis_and_Structure_of_Mono_and_Trinuclear_Zirconocene_Complexes/2256031
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资源简介:
Mono- and trinuclear sumanenyl zirconocene complexes Cp­(sumanenyl)­ZrCl2, Cp*­(sumanenyl)­ZrCl2, and (C21H9)­[(Cp*)­ZrCl2]3 were successfully synthesized. In the mononuclear complexes, convex binding with disturbed η5-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes.
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2014-09-10
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