Synthesis of the [5−7−6] Tricyclic Core of Guanacastepene A via an Intramolecular Mukaiyama Aldol Reaction
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https://figshare.com/articles/dataset/Synthesis_of_the_5_7_6_Tricyclic_Core_of_Guanacastepene_A_via_an_Intramolecular_Mukaiyama_Aldol_Reaction/3746760
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资源简介：
A synthesis of the tricyclic [5−7−6] skeleton of guanacastepene A is described. The six-membered ring of guanacastepene A was constructed
by a Diels−Alder reaction. After several functional group transformations, it was coupled to β-iodocyclopentenone. Lithium dimethylcuprate
conjugate addition followed by an intramolecular Mukaiyama aldol reaction furnished the desired [5−7−6] tricyclic ring system.
创建时间：
2016-08-20
