Nickel-Catalyzed Suzuki–Miyaura Coupling of Heteroaryl Ethers with Arylboronic Acids
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https://figshare.com/articles/dataset/Nickel_Catalyzed_Suzuki_Miyaura_Coupling_of_Heteroaryl_Ethers_with_Arylboronic_Acids/2413981
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资源简介:
Nickel-catalyzed
Suzuki–Miyaura coupling of heteroaryl ethers
with arylboronic acids was described. Selective activation of the
phenol C–O bonds was achieved by converting them into the corresponding
aryl 2,4-dimethoxy-1,3,5-triazine-6-yl ethers, in which aryl C–O
bond could be selectively cleaved with inexpensive, air-stable NiCl2(dppf) as a catalyst. Coupling of these readily accessible
heteroaryl ethers proved tolerant of extensive functional groups.
创建时间:
2016-02-19



