A Multiple Hydrogen-Bond Scaffold Based on Dipyrimidin-2-ylamine
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https://figshare.com/articles/dataset/A_Multiple_Hydrogen-Bond_Scaffold_Based_on_Dipyrimidin-2-ylamine/3740622
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资源简介:
A multiple hydrogen-bond array based on dipyrimidin-2-ylamine is presented, which is easily accessible. The influence of a preorganizing
intramolecular hydrogen bond, tautomeric equilibria, and steric effects on the association behavior were investigated. X-ray diffraction shows
that the molecules feature an ADA (acceptor−donor−acceptor) array of hydrogen-bonding sites in the solid state. The array persists in solution,
and 1H NMR titrations show that molecules with sterically nondemanding DAD arrays are selectively bound.
创建时间:
2016-08-20



