Regioselective Synthesis of Methylene-Bridged Naphthalene Oligomers and Their Host–Guest Chemistry
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https://figshare.com/articles/dataset/Regioselective_Synthesis_of_Methylene-Bridged_Naphthalene_Oligomers_and_Their_Host_Guest_Chemistry/5383891
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资源简介：
In
this research, we report the regioselective synthesis of methylene-bridged
naphthalene oligomers from 2,6-dialkoxyl naphthanene and paraformaldehyde
by using p-TsOH as the catalyst and CH2Cl2 as the solvent. The structures were characterized
by NMR spectroscopy and X-ray crystallography. Their host–guest
chemistry with organic cations was studied, and optimal naphthalene
numbers in the oligomers were revealed for different guests. In addition,
the reason for the unsuccessful synthesis of methylene-bridged naphthalene
macrocycles was discussed.
创建时间：
2017-09-07
