New light on acetone: a master equation model for gas phase photophysics and photochemistry
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This paper presents a unified model of gas phase acetone photophysics and photochemistry that is based on experimental data, which are reviewed and discussed in detail, and a detailed microcanonical master equation formulation. The model accounts for experimental measurements in molecular beams as well as in thermal systems, leads to a new interpretation of some experiments, and reveals a fundamental property of quantum yield measurements that are relevant to atmospheric chemistry. It also furnishes a platform for future theoretical and experimental developments.
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Barker, John R.创建时间:
2021-08-31



