Transannular O‑Heterocyclization: A Useful Tool for the Total Synthesis of Murisolin and 16,19-cis-Murisolin
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Transannular_i_O_i_Heterocyclization_A_Useful_Tool_for_the_Total_Synthesis_of_Murisolin_and_16_19_i_cis_i_Murisolin/2468491
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Transannular O-heterocyclization is applied as a key step in a total synthesis. This highly stereoselective and metal-free transformation introduces four stereocenters in one step. It was chosen to be the pivotal step in the synthesis of Murisolin and 16,19-cis-Murisolin, two annonaceous acetogenins. The efficiency of this synthesis is further illustrated by a stereodivergent late-stage separation of both synthetic routes.
创建时间：
2016-02-20
