An Approach toward Constructing the Trioxadispiroketal Core in the DEF-Ring of (+)-Spirastrellolide A
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https://figshare.com/articles/dataset/An_Approach_toward_Constructing_the_Trioxadispiroketal_Core_in_the_DEF_Ring_of_Spirastrellolide_A/2257726
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资源简介:
A concise
and stereoselective synthesis of the trioxadispiroketal
motif that embodies the DEF-ring of the marine macrolide (+)-spirastrellolide
A is described. The synthetic approach features a sequence of cyclic
acetal tethered ring-closing metathesis and Suárez oxidative
cyclization, thereby constituting a viable strategy for constructing
the Northern Half.
创建时间:
2016-02-16



