Ru(II)-Catalyzed C7 Trifluoromethylthiolation and Thioarylation of Indolines Using Bench-Stable Reagents
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https://figshare.com/articles/dataset/Ru_II_-Catalyzed_C7_Trifluoromethylthiolation_and_Thioarylation_of_Indolines_Using_Bench-Stable_Reagents/27245380
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资源简介：
A Ru(II)-catalyzed C(sp2)-H trifluoromethylthiolation
and thioarylation of indolines using bench-stable reagents have been
explored. Diversely substituted indolines were functionalized at C7
position in good to excellent yields. Radical quenching, deuterium
labeling, KIE, and reaction order determination experiments were performed
to support the proposed reaction pathway. Gram-scale synthesis and
post-transformation of the synthesized products have also been carried
out to demonstrate the applicability of the developed catalytic protocol.
创建时间：
2024-10-16
