Toward a Stable Hydroxyphosphorane
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Toward_a_Stable_Hydroxyphosphorane/3741045
下载链接
链接失效反馈官方服务：
资源简介：
Hydroxy-pentaoxy-phosphoranes are transient intermediates formed during the hydrolysis of various phosphoesters. Kinetic analyses support
the existence of such compounds, although they are not isolated. In an attempt to create a stable example, 2 equiv of a ligand possessing
a very high effective molarity were attached to a central phosphorus. Instead of obtaining a hydroxyphosphorane, analysis by 31P and 19F NMR
spectroscopy and X-ray crystallography showed the product to be a phosphotriester. The reason for this is discussed.
创建时间：
2016-08-20
