Ruthenium Amidinato−Carbene Complexes Containing a Ru−Si Bond: Formation and Reversible α-Silyl Group Migration from the Metal to the Carbene Ligand
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https://figshare.com/articles/dataset/Ruthenium_Amidinato_Carbene_Complexes_Containing_a_Ru_Si_Bond_Formation_and_Reversible_-Silyl_Group_Migration_from_the_Metal_to_the_Carbene_Ligand/3767499
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资源简介：
Reactions of the coordinatively unsaturated
complexes [(η6-C6Me6)Ru{η-iPrNC(Me)NiPr}]+X- with
Me3SiCHN2 resulted in the formation of the amidinato−carbene complexes in which a trimethylsilyl group is
bonded to the ruthenium atom. Migration of the silyl
group to the carbene ligand occurred on reaction with
CO, whereas the reverse reaction was promoted by
photochemical dissociation of CO.
创建时间：
2016-08-26
