Copper(II)-Catalyzed Direct Dioxygenation of Alkenes with Air and N‑Hydroxyphthalimide: Synthesis of β‑Keto‑N‑alkoxyphthalimides
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https://figshare.com/articles/dataset/Copper_II_Catalyzed_Direct_Dioxygenation_of_Alkenes_with_Air_and_i_N_i_Hydroxyphthalimide_Synthesis_of_Keto_i_N_i_alkoxyphthalimides/2175982
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Copper(II)-catalyzed direct dioxygenation of alkenes using air and a simple N-hydroxyphthalimide leading to β-keto-N-alkoxyphthalimides has been developed. The reaction system is mild, efficient, and effective at room temperature with broad substrate scope and substantial steric hindrance. The radical-trapping and 18O-labeling experiments have been demonstrated.
创建时间:
2016-02-13



