Anionic Heptadecanuclear Silver(I) Cluster Constructed from in Situ Generated 2-Mercaptobenzoic Acid and a Sulfide Anion
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https://figshare.com/articles/dataset/Anionic_Heptadecanuclear_Silver_I_Cluster_Constructed_from_in_Situ_Generated_2_Mercaptobenzoic_Acid_and_a_Sulfide_Anion/2570152
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资源简介：
A novel anionic heptadecanuclear silver(I) cluster, (NH4)17[(μ6-S)@Ag17(mba)16]·22H2O (1; H2mba
= 2-mercaptobenzoic
acid), was obtained by the reaction of equivalent molar silver oxide
and 2,2′-dithiodibenzoic acid (H2dtba) under ultrasonic
conditions at 50 °C. Complex 1 is a discrete cluster
comprised of unexpected mba ligands on the shell and a μ6-S2– ion in the core, suggesting the occurrence
of in situ S–S and S–C(sp2) bond cleavages
of the H2dtba ligand. This novel cluster displays moderate
orange-red emission in the solid state at room temperature.
创建时间：
2016-02-22
