Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/Mono_arene_Complexes_of_Thallium_I_Supported_by_a_Weakly_Coordinating_Anion/12073215
下载链接
链接失效反馈官方服务：
资源简介：
Discrete cationic mono(arene) complexes of thallium(I), [Tl(Cp2Fe)]+ and [Tl(C6Me6)]+, were
synthesized as [H2N{B(C6F5)3}2]- salts. The Tl···centroid distance of 2.723 Å to the arene in [Tl(C6Me6)]+ is the shortest described to date. This remarkably strong arene π-bonding is confirmed by DFT
calculations, which give a Tl−C6Me6 interaction energy of 163 kJ mol-1.
创建时间：
2007-03-26
