Formation and Reactivity of Transient Phosphanoxyl Manganese Complexes
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https://figshare.com/articles/dataset/Formation_and_Reactivity_of_Transient_Phosphanoxyl_Manganese_Complexes/7260560
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资源简介：
Formation
of thermally unstable complexes [Mn(CO)2CpMe(R2PO-TEMP)] (Cp = cyclopentadienyl; Me = methyl;
TEMP = 2,2,6,6-tetramethyl-piperidin-1-oxyl) is presented in this
experimental and theoretical study; in case of R = Cy 31P NMR spectroscopic evidence is provided. Mechanistic details of
the product formation and decomposition, due to a homolytic O–N
bond cleavage, are revealed by high-level density functional theory
calculations. Insights into stability and spin density distribution
of transient phosphanoxyl complexes [Mn(CO)2CpMe(R2PO·)] and preliminary results on the acidity of
related complexes [Mn(CO)2CpMe(R2P–OH)] and [W(CO)5(R2P–OH)] toward
TEMP–H are presented.
创建时间：
2018-10-26
