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Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures

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https://figshare.com/articles/dataset/Directly_Pd_II_Bridged_Porphyrin_Belts_with_Remarkable_Curvatures/2737927
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A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki−Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C−H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.
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2010-09-01
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