Potassium-Catalyzed Hydrosilylation of Activated Olefins: Evidence for a Silyl Migration Mechanism
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https://figshare.com/articles/dataset/Potassium_Catalyzed_Hydrosilylation_of_Activated_Olefins_Evidence_for_a_Silyl_Migration_Mechanism/3188080
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资源简介：
The
alkali-metal silyl [K(L)SiPh3] (1;
L = 18-crown-6 ether) catalyzed the hydrosilylation of activated CC
double bonds. Isolation and characterization of an addition product
is in agreement with the anti-Markovnikov selectivity. Second-order
kinetics for the hydrosilylation of 1,1′-diphenylethylene and
the kinetic isotope effect of kH/kD = 3.1 indicate that a silyl migration mechanism
is operative.
创建时间：
2016-05-03
