Enantio- and Diastereoselective, Stereospecific Mannich-Type Reactions in Water
收藏NIAID Data Ecosystem2026-03-06 收录
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Catalytic asymmetric Mannich-type reactions in water proceeded in high yields and selectivities using a combination of ZnF2 and a chiral diamine that has the methoxy groups on the aromatic rings. In these reactions, either syn- or anti-Mannich adducts were stereospecifically obtained from (E)- or (Z)-silicon enolate, in contrast with most asymmetric Mannich-type reactions.
创建时间：
2016-05-06
