Synthesis and Characterization of a 2,6-Diiminophenylgermanium(II) Hydroxide, Azide, and Triazaphospole
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_2_6_Diiminophenylgermanium_II_Hydroxide_Azide_and_Triazaphospole/2374309
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资源简介:
The
reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl]
(1; L = 2,6-(HCNAr)2C6H3, Ar = 2,6-Pri2C6H3) with Me3SnOH and NaN3 in THF afforded [LGeOH(SnMe3Cl)] (2) and [LGeN3] (3), respectively. Compound 3 underwent an uncatalyzed
1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to
afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).
创建时间:
2016-02-18



