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Doping-Induced Structure Variation of 1,3-Cyclohexane− Bis(methylamine)-Templated Zinc−Phosphorus Open Structures

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https://figshare.com/articles/dataset/Doping-Induced_Structure_Variation_of_1_3-Cyclohexane_Bis_methylamine_-Templated_Zinc_Phosphorus_Open_Structures/4008564
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资源简介:
By using 1,3-cyclohexane−bis(methylamine) (CHBMA) as the template, a novel zinc phosphatophosphite (TJPU-3) with extra-large 20-ring channels was synthesized. Cobalt doping produced a bimetallic phosphite (TJPU-6) with 12-ring apertures. While the templates sit in the cis configuration in TJPU-3, they are in the trans configuration in TJPU-6. This result has the potential for separation and recognition of CHBMA isomers.
创建时间:
2016-10-12
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