Linear Bis(perfluoroalkyl) Complexes of Nickel Bipyridine
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Three new complexes were prepared: [(dtbpy)Ni(CF3)2] (1), [(dtbpy)Ni(CF2CF3)2] (2), and [(dtbpy)Ni(CH3)2] (3) (dtbpy = 4,4′-di-tert-butyl-2,2′-bipyridine). Remarkable differences in the structure, electronics, reactivity, and absorption of visible light for the alkyl versus perfluoroalkyl complexes were observed and are detailed in this report.
创建时间：
2016-02-22
