Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts
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https://figshare.com/articles/dataset/Formation_of_Cationic_Intermediates_upon_the_Activation_of_Bis_imino_pyridine_Nickel_Catalysts/2426329
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资源简介:
The
activation of bis(imino)pyridine nickel(II) dichloride complexes
[LNiCl2] with methylalumoxane (MAO) and AlMe3/[CPh3][B(C6F5)4] was
studied by multinuclear NMR spectroscopy. Formation of similar outer-sphere
ion pairs of the types [LNiMe]+[MeMAO]− and [LNiMe]+[B(C6F5)4]−, capable of promoting norbornene polymerization,
was observed.
创建时间:
2016-02-19



