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Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Formation_of_Cationic_Intermediates_upon_the_Activation_of_Bis_imino_pyridine_Nickel_Catalysts/2426329
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The activation of bis­(imino)­pyridine nickel­(II) dichloride complexes [LNiCl2] with methylalumoxane (MAO) and AlMe3/[CPh3]­[B­(C6F5)4] was studied by multinuclear NMR spectroscopy. Formation of similar outer-sphere ion pairs of the types [LNiMe]+[MeMAO]− and [LNiMe]+[B­(C6F5)4]−, capable of promoting norbornene polymerization, was observed.
创建时间:
2016-02-19
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