A Counterion-Directed Approach to the Diels-Alder Paradigm: Cascade Synthesis of Tricyclic Fused Cyclopropanes
收藏NIAID Data Ecosystem2026-03-11 收录
数据链接：
官方服务：
资源简介：
An approach to the intramolecular Diels–Alder reaction has led to a cascade synthesis of complex carbocycles composed of three fused rings and up to five stereocenters with complete stereocontrol. Computational analysis reveals that the reaction proceeds by a Michael/Michael/cyclopropanation/epimerization cascade in which size and coordination of the counterion is key. This date set contains DFT optimised structures as described in the title paper.
创建时间：
2020-01-21
