Cu(II)-Catalyzed Aerobic Hydroperoxidation of Meldrum’s Acid Derivatives and Application in Intramolecular Oxidation: A Conceptual Blueprint for O<sub>2</sub>/H<sub>2</sub> Dihydroxylation
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Aerobic hydroperoxidation of Meldrum’s acid derivatives via a Cu(II)-catalyzed process is presented. The mild reaction conditions are tolerant to pendant unsaturation allowing the formation of endoperoxides via electrophilic activation. Cleavage of the O–O bond provides 1,n-diols with differentiation of the hydroxy groups.
创建时间：
2012-12-07
