Flash Communication: Unexpected Oxidative Alkene Cleavage Behavior of a Molecular Molybdenum Bis(dithiolene) Catalyst
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https://figshare.com/articles/dataset/Flash_Communication_Unexpected_Oxidative_Alkene_Cleavage_Behavior_of_a_Molecular_Molybdenum_Bis_dithiolene_Catalyst/28868391
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资源简介：
Whereas homogeneous molybdenum catalysis typically promotes
alkene
epoxidation with peroxide oxidants, here, a molybdenum bis(dithiolene)
compound is shown to instead catalyze oxidative alkene cleavage, resulting
in carbonyl products akin to ozonolysis reactions. A mechanism involving
O2 transfer from a Mo(O)(η2-O2) intermediate to the alkenes to form 1,2-dioxetanes is proposed
with support from DFT calculations.
创建时间：
2025-04-25
