Diene-Transmissive Cycloadditions: Control of Monocycloaddition by Self-Assembly on a Lewis Acid Template
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https://figshare.com/articles/dataset/Diene_Transmissive_Cycloadditions_Control_of_Monocycloaddition_by_Self_Assembly_on_a_Lewis_Acid_Template/3026653
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资源简介：
The sequential control of diene-transmissive Diels−Alder reactions to expand their versatility for natural product synthesis and the preparation
of diversity oriented libraries is described. Self-assembly of the components (trienol 5 and methyl acrylate) via a Lewis acid template proceeds
with regio-, diastereo-, and enantioselective [(S)-BINOL added] control to the monoadduct. In contrast, no cycloaddition reaction occurred at
22 °C in the absence of catalyst. This protocol obliterates the necessity of tether installation for an intramolecular cyclization.
创建时间：
2007-02-15
