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Ring-Opening Reactions of Aromatic N-Heterocycles by Scandium and Yttrium Alkyl Complexes

NIAID Data Ecosystem2026-03-06 收录

数据链接：

https://figshare.com/articles/dataset/Ring_Opening_Reactions_of_Aromatic_N_Heterocycles_by_Scandium_and_Yttrium_Alkyl_Complexes/2933380 数据链接链接失效反馈

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资源简介：

Ring-Opening Reactions of Aromatic N-Heterocycles by Scandium and Yttrium Alkyl Complexes

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创建时间：

2008-06-18

不对称合成

催化反应

An enantioselective N-heterocyclic carbene (NHC)-catalysed formal [3+2] cycloaddition has been developed for the synthesis of oxazolindin-4-one products. The reaction of oxaziridines and α-aroyloxyald

DataCite Commons2024-03-20 更新150

Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]

有机金属化学

化合物稳定性

The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn

NIAID Data Ecosystem40

The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

不对称催化

有机金属化学

The isolation and structural characterization of metallacyclic allyl (2a) and crotyl (2b) iridium complexes are reported. Complexes 2a and 2b are rare examples of iriduim allyl complexes that undergo

NIAID Data Ecosystem20

Organometallic Derivatives of Orotic Acid. CO−Labilizing Ability of the Amido Group in Chromium and Tungsten Carbonyl Complexes

有机金属化学

反应动力学

Novel orotic acid and uracil derivatives of tungsten and chromium(0), [Et4N]2[Cr(CO)4(orotate)] (1), [Et4N]2[W(CO)4(orotate)] (2), [Et4N]2[W(CO)4(dihydroorotate)] (3), and [Et4N][W(CO)5(uracilate)] (4

NIAID Data Ecosystem50

Intramolecular C–C Bond Coupling of Nitriles to a Diimine Ligand in Group 7 Metal Tricarbonyl Complexes

有机金属化学

C-C偶联反应

Dissolution of M(CO)3(Br)(LAr) [LAr = (2,6-Cl2-C6H3-NCMe)2CH2] in either acetonitrile [M = Mn, Re] or benzonitrile (M = Re) results in C–C coupling of the nitrile to the diimine ligand. When reacted

NIAID Data Ecosystem20

Ring-Opening Reactions of Aromatic N-Heterocycles by Scandium and Yttrium Alkyl Complexes

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