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Azaarenes: 13 Rings in a Row by Cyclopentannulation [data]

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heiDATA2023-01-01 更新2026-05-11 收录
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Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald-Hartwig coupling of previously reported di- and tetrabrominated cyclopentannulated N,N'-dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six-membered rings in a row and a length of 3.1 nm. Their optoelectronic and semi-conducting properties as well as their aromaticity were investigated.

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2023-01-01
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