Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry

A noncatenated, Zn-based metal−organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using “click” chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were “clicked” onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.