A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne
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https://figshare.com/articles/dataset/A_Metal_Templated_4_2_Cycloaddition_Reaction_of_an_Alkyne_and_a_Diyne_To_Form_a_1_2_Aryne/2828674
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资源简介:
Coordination of bis-phosphino diyne substrates to mixed platinum and tungsten metal templates results in a templated 4 + 2 alkyne−diyne cycloaddition reaction to form an aryne intermediate, which abstracts two H atoms to form an arene ring. The aryne intermediate can also be trapped via a Diels−Alder reaction with furan.
创建时间:
2016-02-25



