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Unprecedented Bending and Rearrangement of f-Element Sandwich Complexes Induced by Superbulky Cyclooctatetraenide Ligands

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NIAID Data Ecosystem2026-03-06 收录
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The use of the superbulky cyclooctatetraenide dianion ligand [C8H6(SiPh3)2]2− (= COTBIG) in organo-f-element chemistry leads to unprecedented effects such as the formation of a significantly bent anionic CeIII sandwich complex, a novel cerocene formed by sterically induced SiPh3 group migration, as well as the first example of a bent uranocene.

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2011-02-09
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