Dehydrogenation Tuning of Ammine Borohydrides Using Double-Metal Cations
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https://figshare.com/articles/dataset/Dehydrogenation_Tuning_of_Ammine_Borohydrides_Using_Double_Metal_Cations/2669086
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The strategy of using double-cations to tune the temperature and purity of dehydrogenation of ammine borohydrides is reported. The first double-cation ammine borohydride, Li2Al(BH4)5·6NH3, which forms a novel structure with ordered arrangement of Al(NH3)63+ ammine complexes and Li2(BH4)53− complex anions, is found to release over 10.0 wt % hydrogen below 120 °C with favorable kinetics and high H-purity (>99%).
创建时间:
2016-02-23



